Development of Novel Hydrogen-Bond Donor Catalysts

This work describes novel, effective hydrogen-bond (HB) donor catalysts based on a known bifunctional tertiary amine-thiourea, a privileged structure, which has been proven to be one of the most widely used organocatalysts. These HB donor catalysts derived from quinazoline and benzothiadiazine were...

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Main Author: Inokuma, Tsubasa. (Author, http://id.loc.gov/vocabulary/relators/aut)
Corporate Author: SpringerLink (Online service)
Language:English
Published: Tokyo : Springer Japan : Imprint: Springer, 2013.
Edition:1st ed. 2013.
Series:Springer Theses, Recognizing Outstanding Ph.D. Research,
Subjects:
Online Access:https://doi.org/10.1007/978-4-431-54231-5
Table of Contents:
  • Introduction
  • Development of HB donor catalysts
  • Development and properties of novel HB donor catalysts
  • Asymmetric Michael addition to alpha,beta-unsaturated imides catalyzed by HB donors
  • Asymmetric Hydrazination of activated methylene compounds catalyzed by HB donors
  • Development of hydroxy thiourea catalysts
  • Asymmetric Michael addition of gamma-hydroxyenones and alkenylboronic acids
  • Asymmetric Petasis Reaction of N-aryl-alpha-iminoamides and Alkenylboronates
  • Conclusion.