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03362nam a22005175i 4500 |
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978-3-319-21036-0 |
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DE-He213 |
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20210617131907.0 |
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cr nn 008mamaa |
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150728s2016 gw | s |||| 0|eng d |
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|a 9783319210360
|9 978-3-319-21036-0
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|a 10.1007/978-3-319-21036-0
|2 doi
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|a QD505
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|a 541.395
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|a Liptrot, David J.
|e author.
|4 aut
|4 http://id.loc.gov/vocabulary/relators/aut
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|a Group 2 Mediated Dehydrocoupling
|h [electronic resource] /
|c by David J Liptrot.
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| 250 |
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|a 1st ed. 2016.
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| 264 |
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1 |
|a Cham :
|b Springer International Publishing :
|b Imprint: Springer,
|c 2016.
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| 300 |
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|a XV, 162 p. 169 illus., 3 illus. in color.
|b online resource.
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| 336 |
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|a text
|b txt
|2 rdacontent
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| 337 |
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|a computer
|b c
|2 rdamedia
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| 338 |
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|a online resource
|b cr
|2 rdacarrier
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| 347 |
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|a text file
|b PDF
|2 rda
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| 490 |
1 |
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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| 505 |
0 |
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|a Introduction -- Group 1-Group 2 Bimetallic Alkyls and Hydrides -- Silicon-nitrogen Dehydrocoupling -- Boron-nitrogen Dehydrocoupling -- Single Electron Transfer Steps in Group 2 Catalysis -- Summary -- Future Work.
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| 520 |
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|a This book presents an in-depth study into the utility of σ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with σ-bond metathesis allows a novel hydrogen release from silanes.
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| 650 |
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|a Catalysis.
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| 650 |
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|a Organometallic chemistry .
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| 650 |
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|a Chemistry, Physical and theoretical.
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| 650 |
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|a Catalysis.
|0 https://scigraph.springernature.com/ontologies/product-market-codes/C29000
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| 650 |
2 |
4 |
|a Organometallic Chemistry.
|0 https://scigraph.springernature.com/ontologies/product-market-codes/C19020
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| 650 |
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|a Theoretical and Computational Chemistry.
|0 https://scigraph.springernature.com/ontologies/product-market-codes/C25007
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| 710 |
2 |
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|a SpringerLink (Online service)
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| 773 |
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|t Springer Nature eBook
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| 776 |
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|i Printed edition:
|z 9783319210353
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| 776 |
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|i Printed edition:
|z 9783319210377
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| 776 |
0 |
8 |
|i Printed edition:
|z 9783319370330
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| 830 |
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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| 856 |
4 |
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|u https://doi.org/10.1007/978-3-319-21036-0
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| 912 |
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|a ZDB-2-CMS
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| 912 |
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|a ZDB-2-SXC
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| 950 |
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|a Chemistry and Materials Science (SpringerNature-11644)
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| 950 |
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|a Chemistry and Material Science (R0) (SpringerNature-43709)
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