In-situ Structure Characterization of Elastomers during Deformation and Fracture

This thesis offers novel insights into the time-dependent structural evolution of polymers under deformation. In-situ tensile experiments at high-brilliance synchrotron sources allowed to characterize the material with unrivaled resolution in time and space. The strain-induced crystallization in nat...

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Main Author: Brüning, Karsten. (Author, http://id.loc.gov/vocabulary/relators/aut)
Corporate Author: SpringerLink (Online service)
Language:English
Published: Cham : Springer International Publishing : Imprint: Springer, 2014.
Edition:1st ed. 2014.
Series:Springer Theses, Recognizing Outstanding Ph.D. Research,
Subjects:
Online Access:https://doi.org/10.1007/978-3-319-06907-4
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245 1 0 |a In-situ Structure Characterization of Elastomers during Deformation and Fracture  |h [electronic resource] /  |c by Karsten Brüning. 
250 |a 1st ed. 2014. 
264 1 |a Cham :  |b Springer International Publishing :  |b Imprint: Springer,  |c 2014. 
300 |a XIV, 124 p. 82 illus., 51 illus. in color.  |b online resource. 
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490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5053 
505 0 |a Introduction -- Motivation and Objectives -- Experimental -- Results -- Conclusion and Outlook -- Appendix. 
520 |a This thesis offers novel insights into the time-dependent structural evolution of polymers under deformation. In-situ tensile experiments at high-brilliance synchrotron sources allowed to characterize the material with unrivaled resolution in time and space. The strain-induced crystallization in natural rubber was studied by wide-angle X-ray diffraction. Special emphasis was put on the establishment of new structure-property relationships to give a more in-depth understanding of the mechanical performance of rubber parts, e.g. in tear fatigue loading. To this end, the kinetics of strain-induced crystallization were investigated, subjecting the material to high strain rates. The local structure around a crack tip was observed by scanning wide-angle X-ray diffraction. Ultra-small angle X-ray scattering served to study filled elastomers under deformation, from specially prepared model filler systems to industrially relevant carbon black filled rubbers. Other methods include electron microscopy coupled with in-situ tensile testing and optical dilatometry to examine cavitation in rubbers. The underlying theory as well as a literature review are covered by an extensive introductory chapter, followed by a description of the experimental techniques. The results are presented in more detail than in the original journal publications.  . 
650 0 |a Polymers  . 
650 0 |a Condensed matter. 
650 0 |a Materials science. 
650 0 |a Ceramics. 
650 0 |a Glass. 
650 0 |a Composites (Materials). 
650 0 |a Composite materials. 
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650 2 4 |a Condensed Matter Physics.  |0 https://scigraph.springernature.com/ontologies/product-market-codes/P25005 
650 2 4 |a Characterization and Evaluation of Materials.  |0 https://scigraph.springernature.com/ontologies/product-market-codes/Z17000 
650 2 4 |a Ceramics, Glass, Composites, Natural Materials.  |0 https://scigraph.springernature.com/ontologies/product-market-codes/Z18000 
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