03314nam a22005175i 4500 978-4-431-54373-2 DE-He213 20210618005259.0 cr nn 008mamaa 140218s2014 ja | s |||| 0|eng d 9784431543732 978-4-431-54373-2 10.1007/978-4-431-54373-2 doi QD450-882 PNR bicssc SCI013050 bisacsh PNR thema 541 23 Ohashi, Yuji. author. aut http://id.loc.gov/vocabulary/relators/aut Crystalline State Photoreactions [electronic resource] : Direct Observation of Reaction Processes and Metastable Intermediates / by Yuji Ohashi. 1st ed. 2014. Tokyo : Springer Japan : Imprint: Springer, 2014. XI, 208 p. 232 illus., 26 illus. in color. online resource. text txt rdacontent computer c rdamedia online resource cr rdacarrier text file PDF rda Introduction.- Crystalline State Reaction and Reaction Cavity -- Racemizations of Alkyl Groups in Cobaloxime Complex -- Characteristic Processes of Various Racemizations -- Photoisomerization of Alkyl Groups in Cobaloxime Complexes -- Control of Reactivity -- Metastable or Unstable Intermediates in Reversible Processes -- Metastable or Unstable Intermediates in Reversible Processes -- Conclusion. This book focuses on a variety of photochemical  reaction processes in the crystalline state. The crystalline state reaction is a new category of solid state reaction, in which a reaction occurs with retention of the single crystal form. The whole reaction processes were observed directly by X-ray and neutron diffractions.  In this book, not only the structures of metastable intermediates, such as radicals, carbenes, and nitrenes, but also the unstable species of photochromic compounds and photo-excited structures are shown with colored figures of the molecular structures, with more than 200 figures.  The book is an indispensable resource not only for organic, inorganic and physical chemists but also for graduate students, as it furnishes more than 300 references. Physical chemistry. Crystallography. Organic chemistry. Inorganic chemistry. Physical Chemistry. https://scigraph.springernature.com/ontologies/product-market-codes/C21001 Crystallography and Scattering Methods. https://scigraph.springernature.com/ontologies/product-market-codes/P25056 Organic Chemistry. https://scigraph.springernature.com/ontologies/product-market-codes/C19007 Inorganic Chemistry. https://scigraph.springernature.com/ontologies/product-market-codes/C16008 SpringerLink (Online service) Springer Nature eBook Printed edition: 9784431543749 Printed edition: 9784431543725 Printed edition: 9784431561293 https://doi.org/10.1007/978-4-431-54373-2 ZDB-2-CMS ZDB-2-SXC Chemistry and Materials Science (SpringerNature-11644) Chemistry and Material Science (R0) (SpringerNature-43709)